Surprisingly few people know optimal strategies of Tic-Tac-Toe. It's here:
http://mycanes.miami.edu/~r.aycock/ttt.pdf
It's actually pretty good, considering that it's the only place where I could find comprehensive information about the optimal for the SECOND player. Even the first player can sometimes fall into a trap.
If you feel REALLY evil, mix and match center and corner starts as player 1 and try to use a different corner whenever you can. This will make it harder to pick your strategies apart. You can even pick the edge a few times. Just be sure not to fall into a trap yourself then!
